Sanjay V. Malhotra and Herbert C. Brown Pages 383 - 385 ( 3 )
A convenient and simple method for synthesis of primary amines has been developed by direct amination of B- Chlorodialkylboranes. This general procedure has been applied to synthesize acyclic, cyclic, hindered and chiral amines in very high yields using both hydroxylamine-O-sulfonic acid and monochloroamine as reagents.
Amination, B-Chlorodialkylboranes, chiral amine, organoborane, hydroxy-lamine-O-sulfonic, nitrogen, alkyl group, methyldialkylborane, chlorodialkylborane, water
Laboratory of Synthetic Chemistry, SAIC-Frederick Inc., National Cancer Institute, 1050 Boyles Street, Frederick, Maryland - 21702, USA.