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Formation of Highly Functionalized Hydrindanes and Hydroazulenes via Polyene Cyclization Promoted by the Cross Conjugated α-Carbomethoxy Enone System

[ Vol. 2 , Issue. 4 ]

Author(s):

Hsing-Jang Liu, Daqing Sun, Floria Roa-Gutierrez and Kak-Shan Shia   Pages 364 - 366 ( 3 )

Abstract:


The polyene cyclization promoted by the cross conjugated α-carbomethoxy enone system has been successfully applied to facilitate the construction of the hydridane and hydroazulene framework containing a high level of functionalization.

Keywords:

polyenes, cyclization, bicyclic aliphatic compounds, hydridanes, hydroazulenes, steroidal compounds

Affiliation:

Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 30013, ROC.



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