Animesh Roy, Bilal A. Bhat and Salvatore D. Lepore* Pages 689 - 696 ( 8 )
Organometallic moieties attached to substrates via π-complexation play an important role as auxiliaries. As described in the present review, η-linked auxiliaries have been employed to overcome numerous synthesis obstacles that continue to present significant challenges for catalyzed reactions. This has been particularly true in carbon-carbon bond forming reactions involving highly unsaturated systems such as arenes, dienes and allenes, which are emphasized here.
Organometallic, auxiliaries, chromium tricarbonyl, arenes, dienes, allenes.
Department of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, Florida 33431, Medicinal Chemistry Division, CSIR-Indian Institute of Integrative Medicine, Sanatnagar, Srinagar 190005, Department of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, Florida 33431