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Carbon-Carbon Bond Formation Facilitated by π-Complexed Organometallic Auxiliaries: An Overview

[ Vol. 16 , Issue. 9 ]

Author(s):

Animesh Roy, Bilal A. Bhat and Salvatore D. Lepore*   Pages 689 - 696 ( 8 )

Abstract:


Organometallic moieties attached to substrates via π-complexation play an important role as auxiliaries. As described in the present review, η-linked auxiliaries have been employed to overcome numerous synthesis obstacles that continue to present significant challenges for catalyzed reactions. This has been particularly true in carbon-carbon bond forming reactions involving highly unsaturated systems such as arenes, dienes and allenes, which are emphasized here.

Keywords:

Organometallic, auxiliaries, chromium tricarbonyl, arenes, dienes, allenes.

Affiliation:

Department of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, Florida 33431, Medicinal Chemistry Division, CSIR-Indian Institute of Integrative Medicine, Sanatnagar, Srinagar 190005, Department of Chemistry and Biochemistry, Florida Atlantic University, Boca Raton, Florida 33431

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