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Use and Recyclability of Scandium Tris[bis(perfluorooctylsulfonyl)amide] As A Lewis Acid Promoter for Glycosidation Reactions

[ Vol. 15 , Issue. 12 ]


Takashi Yamanoi*, Ryo Inoue, Yoshiki Oda and Akihiro Yoshida   Pages 1056 - 1059 ( 4 )


In this study, the application of scandium tris[bis(perfluorooctylsulfonyl)amide] as a catalyst in glycosidation reactions was investigated. Besides being a versatile Lewis acid promoter for such reactions, the studied complex could be easily recovered from the reaction mixtures with sufficient activity to repeatedly catalyze the glycosidation reactions.


Glycosidation, Lewis acid, scandium tris[bis(perfluorooctylsulfonyl)amide], in situ reaction, recycle reaction, catalytic reaction, synthesis, glycoside.


Faculty of Pharmacy and Pharmaceutical Sciences, Josai University, 1-1 Keyakidai, Sakado, Saitama 350-0295, Functional Materials Science Research Laboratories, R&D, Lion Corporation, 7-2-1 Hirai, Edogawa-ku, Tokyo 132-0035, Technology Joint Management Office, Tokai University, 4-1-1 Kitakaname, Hiratsuka, Kanagawa 259-1292, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392

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