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Use and Recyclability of Scandium Tris[bis(perfluorooctylsulfonyl)amide] As A Lewis Acid Promoter for Glycosidation Reactions

[ Vol. 15 , Issue. 12 ]

Author(s):

Takashi Yamanoi*, Ryo Inoue, Yoshiki Oda and Akihiro Yoshida   Pages 1056 - 1059 ( 4 )

Abstract:


In this study, the application of scandium tris[bis(perfluorooctylsulfonyl)amide] as a catalyst in glycosidation reactions was investigated. Besides being a versatile Lewis acid promoter for such reactions, the studied complex could be easily recovered from the reaction mixtures with sufficient activity to repeatedly catalyze the glycosidation reactions.

Keywords:

Glycosidation, Lewis acid, scandium tris[bis(perfluorooctylsulfonyl)amide], in situ reaction, recycle reaction, catalytic reaction, synthesis, glycoside.

Affiliation:

Faculty of Pharmacy and Pharmaceutical Sciences, Josai University, 1-1 Keyakidai, Sakado, Saitama 350-0295, Functional Materials Science Research Laboratories, R&D, Lion Corporation, 7-2-1 Hirai, Edogawa-ku, Tokyo 132-0035, Technology Joint Management Office, Tokai University, 4-1-1 Kitakaname, Hiratsuka, Kanagawa 259-1292, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392

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