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ipso-Nitration of Arylboronic Acids with Copper Nitrate and Trifluoroacetic Acid

[ Vol. 15 , Issue. 10 ]

Author(s):

Zhu-Qing Wang, Meng-Ping Guo*, Yong-Ju Wen, Xiu-Li Shen, Mei-Yun Lv and Xiu-Ling Zhou   Pages 891 - 894 ( 4 )

Abstract:


An efficient and novel nitrating reagent has been developed for ipso-nitration of arylboronic acids. By using inexpensive and commercially available Cu(NO3)2/CF3COOH as nitrating reagent, various nitroarenes are produced in moderate to excellent yields (51-96%). Advantages of this procedure are the operational simplicity and no need of extra catalyst.

Keywords:

Arylboronic acids, Cu(NO3)2/CF3COOH as nitrating reagent, ipso-Nitration, nitroarenes, catalyst-free.

Affiliation:

Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun, 336000, Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun, 336000, Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun, 336000, Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun, 336000, Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun, 336000, Institute of Coordination Catalysis, College of Chemistry and Bio-Engineering, Yichun University, Yichun, 336000

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