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Metal-Free HNO3/TEMPO-Catalyzed Conversion of Benzyl Alcohols to Aromatic Nitriles with Oxygen Molecule as the Terminal Oxidant

[ Vol. 15 , Issue. 7 ]

Author(s):

Bo Zhao, Yun-Lai Ren*, Fangping Ren, Xinzhe Tian and Shuang Zhao   Pages 627 - 632 ( 6 )

Abstract:


A non-metal catalytic method for the aerobic conversion of primary alcohols to aromatic nitriles via a single-step operation was developed. A series of primary benzyl alcohols underwent this transformation to give the targeted products in moderate to high yields under the catalysis of TEMPO/ HNO3.

Keywords:

Alcohols, nitriles, catalysis, oxygen, oxidation, non-metal.

Affiliation:

School of Chemical Engineering & Pharmaceutics, Henan University of Science and Technology, Luoyang, Henan 471003, School of Chemical Engineering & Pharmaceutics, Henan University of Science and Technology, Luoyang, Henan 471003, School of Chemical Engineering & Pharmaceutics, Henan University of Science and Technology, Luoyang, Henan 471003, School of Chemical Engineering & Pharmaceutics, Henan University of Science and Technology, Luoyang, Henan 471003, School of Chemical Engineering & Pharmaceutics, Henan University of Science and Technology, Luoyang, Henan 471003

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