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Hydrosilylation of Olefins with the Cp2TiCl2/Sm Catalytic System

[ Vol. 15 , Issue. 12 ]

Author(s):

Xiaoling Yang, Ying Bai*, Jiayun Li, Yu Liu and Jiajian Peng*   Pages 1042 - 1045 ( 4 )

Abstract:


Hydrosilylation of olefins catalyzed by Cp2TiCl2/Sm (Cp = cyclopentadienyl) under solventfree conditions has been investigated. The mole ratio of Cp2TiCl2/Sm has some influence on the catalytic properties, and the best Cp2TiCl2/Sm ratio for the catalytic hydrosilylation is 1/2. By using this catalytic system, hydrogenation products were also detected in the final reaction mixtures.

Keywords:

Alkene, catalytic, hydrosilylation, samarium, solvent-free, titanocene.

Affiliation:

Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121

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