T.P. Charanraj, P. Ramachandra, N. Ramesh and H. Junjappa* Pages 412 - 417 ( 6 )
Acetone-d6 has been transformed for the first time to 4,4-bis(methylthio)but-3-en-2-one- 1,1,1,3-d4. This tetradeutero-α-oxoketenedithioacetal is shown to be an excellent 1,3-dielectrophilic building block for the synthesis of 5- and 6-membered deuterated heterocycles and aromatics.
Acetone-d6, α-oxoketenedithioacetal, 1, 3-dielectrophilic building block, deuterated heterocycles, aromatics, aromatic compounds.
Chemistry Research Unit, REVA Institute of Science and Management, Bangalore-560064, Department of Chemistry, REVA Institute of Technology and Management, Bangalore-560064, Director Planning, REVA University, Bangalore-560064, Chemistry Research Unit, REVA Institute of Science and Management, Bangalore-560064