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Efficient Synthesis of Aromatic Nitriles via Cyanation of Aryl Bromides and K4[Fe(CN)6] Catalyzed by a Palladium(II) Complex

[ Vol. 10 , Issue. 3 ]

Author(s):

Mengping Guo, Junying Ge, Zhiyong Zhu and Xiaochun Wu   Pages 213 - 215 ( 3 )

Abstract:


Cyanation of aryl bromides and K4[Fe(CN)6] were carried out in the presence of catalytic amounts of {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} (PdCl2L2) in DMF and a variety of Aromatic nitriles were obtained in good yields under aerobic conditions.

Keywords:

Aromatic nitriles, cyanation, palladium(II) complex, synthesis

Affiliation:

Institute of Coordination Catalysis, Engineering Center of Jiangxi University for Lithium Energy, Key Laboratory of Jiangxi University for Applied Chemistry and Chemical Biology, Yichun University, Yichun 336000, China.



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