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Efficient Synthesis of Aromatic Nitriles via Cyanation of Aryl Bromides and K4[Fe(CN)6] Catalyzed by a Palladium(II) Complex

[ Vol. 10 , Issue. 3 ]


Mengping Guo, Junying Ge, Zhiyong Zhu and Xiaochun Wu   Pages 213 - 215 ( 3 )


Cyanation of aryl bromides and K4[Fe(CN)6] were carried out in the presence of catalytic amounts of {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} (PdCl2L2) in DMF and a variety of Aromatic nitriles were obtained in good yields under aerobic conditions.


Aromatic nitriles, cyanation, palladium(II) complex, synthesis


Institute of Coordination Catalysis, Engineering Center of Jiangxi University for Lithium Energy, Key Laboratory of Jiangxi University for Applied Chemistry and Chemical Biology, Yichun University, Yichun 336000, China.

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